WebPhenyllithium or lithobenzene is an organometallic agent with the empirical formula C 6 H 5 Li. It is most commonly used as a metalating agent in organic syntheses and a substitute for Grignard reagents for introducing phenyl groups in organic syntheses. Crystalline phenyllithium is colorless; however, solutions of phenyllithium are various shades of … WebThe normality of the phenyllithium solution was determined by titration with standard hydrochloric acid solution. An ethereal solution of phenyllithium (0.018 mole, 50 ml) was added to a cooled solution of pyridine (18 g) in dry …
Phenyllithium - Green - Major Reference Works - Wiley Online Library
Web15. aug 2024 · Phenyllithium is an organometallic compound that is used as a nucleophile for substitution and addition reactions, and in the synthesis of organolithium building … Phenyllithium or lithobenzene is an organometallic agent with the empirical formula C6H5Li. It is most commonly used as a metalating agent in organic syntheses and a substitute for Grignard reagents for introducing phenyl groups in organic syntheses. Crystalline phenyllithium is colorless; however, solutions of … Zobraziť viac Phenyllithium was first produced by the reaction of lithium metal with diphenylmercury: (C6Η5)2Ηg + 2Li → 2C6Η5Li + Ηg Reaction of a phenyl halide with lithium metal produces … Zobraziť viac Phenyllithium is an organolithium compound that forms monoclinic crystals. Solid phenyllithium can be described as consisting of … Zobraziť viac The primary use of PhLi is to facilitate formation of carbon-carbon bonds by nucleophilic addition and substitution reactions: Zobraziť viac spinal cord stimulator psych eval
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WebPhenyllithium has a molecular weight of 84.046 g/mol, a monoisotopic mass of 84.055 g/mol and an exact mass of 84.055 g/mol. It has a heavy atom count of 7 and a complexity of 95.8. Phenyllithium is soluble in ether solvents; it is soluble in hydrocarbon solvents especially through the addition of donor additives/solvents. Uses WebPhenyllithium. Molecular Formula CHLi. Average mass 84.045 Da. Monoisotopic mass 84.055130 Da. ChemSpider ID 10254416. Web23. jan 2024 · The basic reaction involves the nucleophilic attack of the carbanionic carbon in the organometallic reagent with the electrophilic carbon in the carbonyl to form alcohols. Both Grignard and Organolithium Reagents will perform these reactions. Addition to formaldehyde gives 1° alcohols. Addition to aldehydes gives 2° alcohols. spinal cord stimulator market